Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/17810
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Type: | Journal article |
Title: | The gas phase cyclization of deprotonated N-aryl-2-cyano-2-diazoacetamides |
Author: | Lobodin, V. Morzherin, Y. Blumenthal, T. Bilusich, D. Ovcharenko, V. Bowie, J. Lebedev, A. |
Citation: | ARKIVOC, 2005; 4(4):189-198 |
Publisher: | Arkat USA, Inc. |
Issue Date: | 2005 |
ISSN: | 1551-7004 1551-7012 |
Editor: | Stevens, C.V. |
Statement of Responsibility: | Vladislav V. Lobodin, Yuriy Yu. Morzherin, Tom Blumenthal, Daniel Bilusich, Vladimir V. Ovcharenko, John H. Bowie, and Albert T. Lebedev |
Abstract: | 1-Aryl-4-cyano-5-hydroxy-1,2,3-triazoles can be obtained in solution by base-catalysed cyclization of N-aryl-2-cyano-2-diazoacetamides. A similar reaction was shown to take place under conditions of negative ion chemical ionization in the ion source of a mass spectrometer. High resolution mass spectrometry, tandem mass spectrometry, charge reversal spectra, synthesis of the ions with known structures and quantum chemical calculations were used to prove the latter statement. The fact of the observed cyclization demonstrates once again the ability of mass spectrometry to study the gas phase chemical reactions that take place in solution. |
Keywords: | Cyclization diazoamides triazoles gas phase negative ion mass spectrometry |
Description: | The document attached has been archived with permission from the publisher. |
Rights: | Copyright © ARKAT USA, Inc |
DOI: | 10.3998/ark.5550190.0006.415 |
Published version: | http://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/2005/4/ |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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Bowie_17810.pdf | 298.01 kB | Publisher's PDF | View/Open |
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