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https://hdl.handle.net/2440/101152
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Type: | Journal article |
Title: | The biosynthesis and biomimetic synthesis of merochlorins A and B |
Author: | Pepper, H. George, J. |
Citation: | Synlett: accounts and rapid communications in synthetic organic chemistry, 2015; 26(18):2485-2490 |
Publisher: | Georg Thieme Verlag |
Issue Date: | 2015 |
ISSN: | 0936-5214 1437-2096 |
Statement of Responsibility: | Henry P. Pepper, Jonathan H. George |
Abstract: | The interplay between biosynthetic studies and biomimetic synthesis is discussed in the context of the merochlorin family of marine natural products. Total syntheses of merochlorin A by our group and merochlorin B by the Trauner group are presented alongside the biosynthetic studies of Moore and co-workers. The common theme is the generation of complex polycyclic ring systems by oxidative dearomatization–cyclization cascade reactions.The interplay between biosynthetic studies and biomimetic synthesis is discussed in the context of the merochlorin family of marine natural products. Total syntheses of merochlorin A by our group and merochlorin B by the Trauner group are presented alongside the biosynthetic studies of Moore and co-workers. The common theme is the generation of complex polycyclic ring systems by oxidative dearomatization–cyclization cascade reactions. |
Keywords: | Biomimetic synthesis; cascade reactions; natural products; meroterpenoids; oxidative dearomatization |
Rights: | Copyright status unknown |
DOI: | 10.1055/s-0035-1560635 |
Grant ID: | http://purl.org/au-research/grants/arc/DE130100689 |
Published version: | http://dx.doi.org/10.1055/s-0035-1560635 |
Appears in Collections: | Aurora harvest 3 Chemistry publications |
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