Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/104993
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Type: Journal article
Title: Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap
Author: Stassen, I.
Styles, M.
Van Assche, T.
Campagnol, N.
Fransaer, J.
Denayer, J.
Tan, J.
Falcaro, P.
De Vos, D.
Ameloot, R.
Citation: Chemistry of Materials, 2015; 27(5):1801-1807
Publisher: American Chemical Society
Issue Date: 2015
ISSN: 0897-4756
1520-5002
Statement of
Responsibility: 
Ivo Stassen, Mark Styles, Tom Van Assche, Nicolò Campagnol, Jan Fransaer, Joeri Denayer, Jin-Chong Tan, Paolo Falcaro, Dirk De Vos and Rob Ameloot
Abstract: Film deposition is an enabling technology for integration of novel functional materials into real-world practical applications. We report both the anodic and cathodic electrochemical film deposition of UiO-66, a prototype of highly stable, zirconium-based metal−organic frameworks, using zirconium foil as the only metal source. The fundamentally different film formation mechanisms at the cathode and anode result in a significantly different coating adhesion strength, mainly due to the formation of an oxide film serving as a bridging layer at the anode. The patterned deposition capability of the electrochemical method enables the straightforward integration of UiO-66 as a sorbent film in a miniaturized sorbent trap for online analytical sampling and concentration of dilute volatile organic compounds.
Rights: © 2015 American Chemical Society
DOI: 10.1021/cm504806p
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