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|Title:||Host-guest chemistry of linked β- and γ-cyclodextrin dimers and 1- and 2-naphthyl-sulfonamide substituted poly(acrylate)s in aqueous solution|
|Other Titles:||Host-guest chemistry of linked beta- and gamma-cyclodextrin dimers and 1- and 2-naphthyl-sulfonamide substituted poly(acrylate)s in aqueous solution|
|Citation:||Chemistry Select, 2017; 2(4):1421-1430|
|Hamish L. McTernan, Huy T. Ngo, Duc-Truc Pham, a, Philip Clements, Stephen F. Lincoln, Jie Wang, Xuhong Guo and Christopher J. Easton|
|Abstract:||Host-guest complexation by β- and γ-cyclodextrin and their four succinamide-linked dimers of the naphthyl substituents of four randomly substituted poly(acrylate)s in twenty-four aqueous systems has been characterised. Complexation occurs through entry of the naphthyl substituents into the cyclodextrin annuli. The naphthyl substitution position, the length of the tether attaching the naphthyl substituent to the poly(acrylate) backbone and the size and stereochemistry of the cyclodextrin hosts determine the relative stabilities of poly(acrylate) intra-strand complexes in dilute solution and the formation of inter-strand cross-links in more concentrated solution.|
|Keywords:||Cyclodextrin; host-guest systems; polymers; supramolecular chemistry|
|Rights:||© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim|
|Appears in Collections:||Chemistry and Physics publications|
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