Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/105653
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Type: Journal article
Title: Host-guest chemistry of linked β- and γ-cyclodextrin dimers and 1- and 2-naphthyl-sulfonamide substituted poly(acrylate)s in aqueous solution
Other Titles: Host-guest chemistry of linked beta- and gamma-cyclodextrin dimers and 1- and 2-naphthyl-sulfonamide substituted poly(acrylate)s in aqueous solution
Author: McTernan, H.
Ngo, H.
Pham, D.-.T.
Clements, P.
Lincoln, S.
Wang, J.
Guo, X.
Easton, C.
Citation: Chemistry Select, 2017; 2(4):1421-1430
Publisher: Wiley
Issue Date: 2017
ISSN: 2365-6549
2365-6549
Statement of
Responsibility: 
Hamish L. McTernan, Huy T. Ngo, Duc-Truc Pham, a, Philip Clements, Stephen F. Lincoln, Jie Wang, Xuhong Guo and Christopher J. Easton
Abstract: Host-guest complexation by β- and γ-cyclodextrin and their four succinamide-linked dimers of the naphthyl substituents of four randomly substituted poly(acrylate)s in twenty-four aqueous systems has been characterised. Complexation occurs through entry of the naphthyl substituents into the cyclodextrin annuli. The naphthyl substitution position, the length of the tether attaching the naphthyl substituent to the poly(acrylate) backbone and the size and stereochemistry of the cyclodextrin hosts determine the relative stabilities of poly(acrylate) intra-strand complexes in dilute solution and the formation of inter-strand cross-links in more concentrated solution.
Keywords: Cyclodextrin; host-guest systems; polymers; supramolecular chemistry
Rights: © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
RMID: 0030065053
DOI: 10.1002/slct.201601630
Grant ID: http://purl.org/au-research/grants/arc/DP110103177
Appears in Collections:Chemistry and Physics publications

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