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Type: Journal article
Title: Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties
Author: Healey, K.
Liang, W.
Southon, P.
Church, T.
D'Alessandro, D.
Citation: Journal of Materials Chemistry A, 2016; 4(28):10816-10819
Publisher: Royal Society of Chemistry
Issue Date: 2016
ISSN: 2050-7488
Statement of
Katherine Healey, Weibin Liang, Peter D. Southon, Tamara L. Church and Deanna M. D'Alessandro
Abstract: The first example of a spiropyran-incorporated metal–organic framework was synthesised via a two-step post-synthesis modification of the Zr-oxo nodes in MOF-808. The incorporated spiropyran could not otherwise be obtained via the analogous one-step de novo synthesis. The resulting MOF-808-SP showed a photoresponsive surface area, pore volume and CO₂ uptake, relevant for light-dependent gas separations processes.
Rights: This journal is © The Royal Society of Chemistry 2016
DOI: 10.1039/c6ta04160d
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