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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/107086
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dc.contributor.authorBurgun, A.-
dc.contributor.authorCoghlan, C.-
dc.contributor.authorHuang, D.-
dc.contributor.authorChen, W.-
dc.contributor.authorHorike, S.-
dc.contributor.authorKitagawa, S.-
dc.contributor.authorAlvino, J.-
dc.contributor.authorMetha, G.-
dc.contributor.authorSumby, C.-
dc.contributor.authorDoonan, C.-
dc.date.issued2017-
dc.identifier.citationAngewandte Chemie International Edition, 2017; 56(29):8412-8416-
dc.identifier.issn1433-7851-
dc.identifier.issn1521-3773-
dc.identifier.urihttp://hdl.handle.net/2440/107086-
dc.descriptionVersion of record online: February 3, 2017-
dc.description.abstractSingle-crystal X-ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a MnII -based metal-organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn-over in the case of MeI. This work highlights the capability of MOFs to act as platform materials for studying single-site catalysis in heterogeneous systems.-
dc.description.statementofresponsibilityAlexandre Burgun, Campbell J. Coghlan, David M. Huang, Wenqian Chen, Satoshi Horike, Susumu Kitagawa, Jason F. Alvino, Gregory F. Metha, Christopher J. Sumby, and Christian J. Doonan-
dc.language.isoen-
dc.publisherWiley-
dc.rights© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.source.urihttp://dx.doi.org/10.1002/anie.201611254-
dc.subjectcarbonylation-
dc.subjectheterogeneous catalysis-
dc.subjectMOFs-
dc.subjectrhodium complexes-
dc.subjectstructure elucidation-
dc.titleMapping-out catalytic processes in a metal-organic framework with single-crystal X-ray crystallography-
dc.typeJournal article-
dc.identifier.doi10.1002/anie.201611254-
dc.relation.granthttp://purl.org/au-research/grants/arc/DP160103234-
pubs.publication-statusPublished-
dc.identifier.orcidCoghlan, C. [0000-0003-1625-3216]-
dc.identifier.orcidHuang, D. [0000-0003-2048-4500]-
dc.identifier.orcidAlvino, J. [0000-0002-1459-8619]-
dc.identifier.orcidMetha, G. [0000-0003-1094-0947]-
dc.identifier.orcidSumby, C. [0000-0002-9713-9599]-
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Chemical Engineering publications

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