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https://hdl.handle.net/2440/109260
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Type: | Journal article |
Title: | Carbon solving carbon's problems: recent progress of nanostructured carbon-based catalysts for the electrochemical reduction of CO₂ |
Other Titles: | Carbon solving carbon's problems: recent progress of nanostructured carbon-based catalysts for the electrochemical reduction of CO(2) |
Author: | Vasileff, A. Zheng, Y. Qiao, S. |
Citation: | Advanced Energy Materials, 2017; 7(21):1700759-1-1700759-21 |
Publisher: | Wiley-VCH Verlag |
Issue Date: | 2017 |
ISSN: | 1614-6832 1614-6840 |
Statement of Responsibility: | Anthony Vasileff, Yao Zheng, and Shi Zhang Qiao |
Abstract: | The electrochemical reduction of CO₂ to useful molecules offers an elegant technological solution to current energy security and sustainability issues because it sequesters carbon from the atmosphere, provides an energy storage solution for intermittent renewable sources, and can be used to produce fuels and industrial chemicals. Nanostructured carbon materials have been extensively used to catalyse some key electrochemical processes because of their excellent electrical conductivity, chemical stability, and abundant active sites. This progress report focuses on nanostructured carbon materials, namely graphene materials, carbon nanotubes, porphyrin materials, nanodiamond, and glassy carbon, which have recently shown promise as high performing CO₂ reduction electrocatalysts and supports. Along with discussion regarding materials synthesis, structural characterisation, and electrochemical performance characterisation techniques used, this report will discuss the findings of recent computational CO₂RR studies which have been key to elucidating active sites and reaction mechanisms, and developing strategies to break conventional scaling relationships. Lastly, challenges and future perspective of these carbon-based materials for CO₂ reduction applications will be given. Much work is still required to realise the commercial viability of the technology, but advanced experimental techniques coupled with theoretical calculations are expected to facilitate future development of the technology. |
Keywords: | Carbon nanostructures; CO₂ reduction; density functional theory; doping; electrocatalysts |
Rights: | © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/aenm.201700759 |
Grant ID: | http://purl.org/au-research/grants/arc/DP160104866 http://purl.org/au-research/grants/arc/DP170104464 http://purl.org/au-research/grants/arc/LP160100927 |
Published version: | http://onlinelibrary.wiley.com/doi/10.1002/aenm.201700759/abstract |
Appears in Collections: | Aurora harvest 3 Chemical Engineering publications |
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