Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/110867
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Type: Journal article
Title: Perspectives on metal-organic frameworks with intrinsic electrocatalytic activity
Author: Solomon, M.
Church, T.
D'Alessandro, D.
Citation: CrystEngComm, 2017; 19(29):4049-4065
Publisher: The Royal Society of Chemistry
Issue Date: 2017
ISSN: 1466-8033
1466-8033
Statement of
Responsibility: 
Marcello B. Solomon, Tamara L. Church and Deanna M. D'Alessandro
Abstract: This highlight article focuses on the rapidly emerging area of electrocatalytic metal–organic frameworks (MOFs) with a particular emphasis on those systems displaying intrinsic activity. Three electrocatalytic conversion processes are discussed, including CO2 reduction, the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER), as well as a selection of other relevant examples. The scope of our discussion encompasses aspects of MOF structure that are key to their function, performance characteristics such as stability and selectivity, together with methods for interfacing MOFs with surfaces. Key challenges that have emerged are highlighted in addition to opportunities that are relevant to the field in the design of more stable, selective and robust electrocatalysts for a range of industrial processes.
Rights: This journal is © The Royal Society of Chemistry 2017
RMID: 0030078721
DOI: 10.1039/C7CE00215G
Appears in Collections:Chemical Engineering publications

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