Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/110945
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Type: Journal article
Title: Influence of physico-chemical properties of soil clay fractions on the retention of dissolved organic carbon
Author: Singh, M.
Sarkar, B.
Hussain, S.
Ok, Y.
Bolan, N.
Churchman, G.
Citation: Environmental Geochemistry and Health: official journal of the Society for Environmental Geochemistry and Health, 2017; 39(6):1335-1350
Publisher: Springer
Issue Date: 2017
ISSN: 0269-4042
1573-2983
Statement of
Responsibility: 
Mandeep Singh, Binoy Sarkar, Sabir Hussain, Yong Sik Ok, Nanthi S. Bolan, Gordon Jock Churchman
Abstract: This study investigated the effects of surface functional groups, cation exchange capacity (CEC), surface charge, sesquioxides and specific surface area (SSA) of three soil clay fractions (SCFs) (kaolinite-illite, smectite and allophane) on the retention of dissolved organic carbon (DOC) in soils. Physico-chemical properties of the SCFs before and after removing native carbon and/or sesquioxides were characterised, and the DOC adsorption-desorption tests were conducted by a batch method. Native organic carbon (OC)/sesquioxide removal treatments led to a small change in the CEC values of kaolinite-illite, but significant changes in those of smectite and allophane. The net negative surface charge increased in all samples with an increase in pH indicating their variable charge characteristics. The removal of native OC resulted in a slight increase in the net positive charge on soil clay surfaces, while sesquioxide removal increased the negative charge. Changes in the functional groups on the SCF surfaces contributed to the changes in CEC and zeta potential values. There was a strong relationship (R 2 = 0.93, p < 0.05) between the Langmuir maximum DOC adsorption capacity (Q max) and SSA. The Q max value also showed a moderately strong relationship (R 2 = 0.55, p < 0.05) with zeta potential (at pH 7). Q max was only poorly correlated with CEC and native OC content. Therefore, along with SSA, the surface charge and functional groups of SCFs played the key role in determining the adsorption affinity and hence retention of DOC in soils.
Keywords: Adsorption–desorption
Physico-chemical properties
Sesquioxides
Soil carbon sequestration
Soil clay fractions
Rights: © Springer Science+Business Media Dordrecht 2017
DOI: 10.1007/s10653-017-9939-0
Grant ID: http://purl.org/au-research/grants/arc/DP140100323
Appears in Collections:Aurora harvest 3
Earth and Environmental Sciences publications

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