Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/111790
Citations
Scopus Web of Science® Altmetric
?
?
Type: Journal article
Title: Stratospheric ozone intrusion events and their impacts on tropospheric ozone in the Southern Hemisphere
Author: Greenslade, J.
Alexander, S.
Schofield, R.
Fisher, J.
Klekociuk, A.
Citation: Atmospheric Chemistry and Physics, 2017; 17(17):10269-10290
Publisher: Copernicus Publications
Issue Date: 2017
ISSN: 1680-7316
1680-7324
Statement of
Responsibility: 
Jesse W. Greenslade, Simon P. Alexander, Robyn Schofield, Jenny A. Fisher, and Andrew K. Klekociuk
Abstract: Stratosphere-to-troposphere transport (STT) provides an important natural source of ozone to the upper troposphere, but the characteristics of STT events in the Southern Hemisphere extratropics and their contribution to the regional tropospheric ozone budget remain poorly constrained. Here, we develop a quantitative method to identify STT events from ozonesonde profiles. Using this method we estimate the seasonality of STT events and quantify the ozone transported across the tropopause over Davis (69° S, 2006– 2013), Macquarie Island (54° S, 2004–2013), and Melbourne (38° S, 2004–2013). STT seasonality is determined by two distinct methods: a Fourier bandpass filter of the vertical ozone profile and an analysis of the Brunt–Väisälä frequency. Using a bandpass filter on 7–9 years of ozone profiles from each site provides clear detection of STT events, with maximum occurrences during summer and minimum during winter for all three sites. The majority of tropospheric ozone enhancements owing to STT events occur within 2.5 and 3 km of the tropopause at Davis and Macquarie Island respectively. Events are more spread out at Melbourne, occurring frequently up to 6 km from the tropopause. The mean fraction of total tropospheric ozone attributed to STT during STT events is 1:0–3:5% at each site; however, during individual events, over 10% of tropospheric ozone may be directly transported from the stratosphere. The cause of STTs is determined to be largely due to synoptic low-pressure frontal systems, determined using coincident ERA-Interim reanalysis meteorological data. Ozone enhancements can also be caused by biomass burning plumes transported from Africa and South America, which are apparent during austral winter and spring and are determined using satellite measurements of CO. To provide regional context for the ozonesonde observations, we use the GEOS-Chem chemical transport model, which is too coarsely resolved to distinguish STT events but is able to accurately simulate the seasonal cycle of tropospheric ozone columns over the three southern hemispheric sites. Combining the ozonesonde-derived STT event characteristics with the simulated tropospheric ozone columns from GEOS-Chem, we estimate STT ozone flux near the three sites and see austral summer dominated yearly amounts of between 5.7 and 8.7 ×10¹⁷ molecules cm⁻² a⁻¹
Rights: © Author(s) 2017. This work is distributed under the Creative Commons Attribution 3.0 License.
RMID: 0030084702
DOI: 10.5194/acp-17-10269-2017
Grant ID: http://purl.org/au-research/grants/arc/CE1101028
Appears in Collections:Physics publications

Files in This Item:
File Description SizeFormat 
hdl_111790.pdfPublished version2.31 MBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.