Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/113547
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Type: Journal article
Title: Carbon, nitrogen and phosphorus containing metal-free photocatalysts for hydrogen production: progress and challenges
Author: Rahman, M.
Davey, K.
Qiao, S.
Citation: Journal of Materials Chemistry A, 2018; 6(4):1305-1322
Publisher: Royal Society of Chemistry
Issue Date: 2018
ISSN: 2050-7488
2050-7496
Statement of
Responsibility: 
Mohammad Ziaur Rahman, Kenneth Davey and Shi-Zhang Qiao
Abstract: Photocatalytic hydrogen production from water is a green and renewable path for solar fuel production. Hydrogen can be advantageously stored directly and burned without emission of deleterious CO and NO⨯ gases. Photocatalysis therefore shows significant promise as a part solution to a sustainable and affordable energy supply in an era post-fossil fuels. Influenced by the Fujishima–Honda effect, significant advances in photocatalytic hydrogen production have occurred at the laboratory-scale. For wide adoption however, the photocatalysts will need to be made from earth-abundant materials, be stable and scalable from laboratory-to-large-scale, and have high conversion efficiency. In this regard, metalfree photocatalysts show practical promise in meeting these requirements. To foster research in materials design, here we critically review recent significant developments in metal-free photocatalysts consisting of carbon, nitrogen and phosphorus, and discuss how future large-scale hydrogen production via overall water-splitting could be accomplished economically.
Rights: This journal is © The Royal Society of Chemistry 2018
RMID: 0030081540
DOI: 10.1039/c7ta10404a
Grant ID: http://purl.org/au-research/grants/arc/DP140104062
http://purl.org/au-research/grants/arc/DP160104866
http://purl.org/au-research/grants/arc/DP170104464
Appears in Collections:Chemical Engineering publications

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