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|Title:||Spectroscopic, electronic and computational properties of a mixed tetrachalcogenafulvalene and its charge transfer complex|
|Citation:||Journal of Materials Chemistry C, 2018; 6(5):1092-1104|
|Publisher:||Royal Society of Chemistry|
|Robert J. Walwyn, Bun Chan, Pavel M. Usov, Marcello B. Solomon, Samuel G. Duyker, Jin Young Koo, Masaki Kawano, Peter Turner, Cameron J. Kepert and Deanna M. D'Alessandro|
|Abstract:||This paper reports additional properties of the electron donor molecule triselenathiafulvalene (TSTF) and its synthesis via a new route involving the precursor tetracarbomethoxytriselenathiafulvalene (TCMTSTF). The structural, electronic and computational properties of TSTF are fully profiled, and discussed in the context of the closely related archetypal electron donor molecule tetrathiafulvalene (TTF). TSTF was also incorporated into a charge transfer (CT) complex with the well-known electron acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ), to generate TSTF–TCNQ. In order to establish its position in the greater TXF–TCNQ series (where TXF = a tetrachalcogenafulvalene), spectral, electrochemical, magnetic, conductivity and computational studies were performed on TSTF and TSTF–TCNQ to extend what is known about the highly interesting and useful new donor molecule.|
|Rights:||This journal is © The Royal Society of Chemistry 2018|
|Appears in Collections:||Aurora harvest 8|
Chemical Engineering publications
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