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Type: Journal article
Title: Spectroscopic, electronic and computational properties of a mixed tetrachalcogenafulvalene and its charge transfer complex
Author: Walwyn, R.J.
Chan, B.
Usov, P.M.
Solomon, M.B.
Duyker, S.G.
Koo, J.Y.
Kawano, M.
Turner, P.
Kepert, C.J.
D'Alessandro, D.M.
Citation: Journal of Materials Chemistry C, 2018; 6(5):1092-1104
Publisher: Royal Society of Chemistry
Issue Date: 2018
ISSN: 2050-7526
Statement of
Robert J. Walwyn, Bun Chan, Pavel M. Usov, Marcello B. Solomon, Samuel G. Duyker, Jin Young Koo, Masaki Kawano, Peter Turner, Cameron J. Kepert and Deanna M. D'Alessandro
Abstract: This paper reports additional properties of the electron donor molecule triselenathiafulvalene (TSTF) and its synthesis via a new route involving the precursor tetracarbomethoxytriselenathiafulvalene (TCMTSTF). The structural, electronic and computational properties of TSTF are fully profiled, and discussed in the context of the closely related archetypal electron donor molecule tetrathiafulvalene (TTF). TSTF was also incorporated into a charge transfer (CT) complex with the well-known electron acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ), to generate TSTF–TCNQ. In order to establish its position in the greater TXF–TCNQ series (where TXF = a tetrachalcogenafulvalene), spectral, electrochemical, magnetic, conductivity and computational studies were performed on TSTF and TSTF–TCNQ to extend what is known about the highly interesting and useful new donor molecule.
Rights: This journal is © The Royal Society of Chemistry 2018
DOI: 10.1039/c7tc03853d
Grant ID: ARC
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