Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/114174
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dc.contributor.authorZheng, Y.en
dc.contributor.authorJiao, Y.en
dc.contributor.authorQiao, S.en
dc.contributor.authorVasileff, A.en
dc.date.issued2018en
dc.identifier.citationAngewandte Chemie, 2018; 57(26):7568-7579en
dc.identifier.issn1433-7851en
dc.identifier.issn1521-3773en
dc.identifier.urihttp://hdl.handle.net/2440/114174-
dc.description.abstractThe hydrogen evolution reaction (HER) is a fundamental process in electrocatalysis and plays an important role in energy conversion for the development of hydrogen-based energy sources. However, the considerably slow rate of the HER in alkaline conditions has hindered advances in water splitting techniques for high-purity hydrogen production. Differing from well documented acidic HER, the mechanistic aspects of alkaline HER are yet to be settled. Herein, we present a critical appraisal of alkaline HER electrocatalysis, with a special emphasis on the connection between fundamental surface electrochemistry on single crystal models and the derived molecular design principle for real-world electrocatalysts. By presenting some typical examples across theoretical calculations, surface characterization, and electrochemical experiments, we try to address some key ongoing debates to deliver a better understanding of alkaline HER at the atomic level.en
dc.description.statementofresponsibilityYao Zheng, Yan Jiao, Anthony Vasileff, Shi‐Zhang Qiaoen
dc.language.isoenen
dc.publisherWileyen
dc.rights© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheimen
dc.subjectAlkaline hydrogen-evolution reaction; Density-functional theory; Hydrogen adsorption/absorption; electrocatalysis; mechanistic studiesen
dc.titleThe hydrogen evolution reaction in alkaline solution: from theory, single crystal models, to practical electrocatalystsen
dc.typeJournal articleen
dc.identifier.rmid0030078553en
dc.identifier.doi10.1002/anie.201710556en
dc.relation.granthttp://purl.org/au-research/grants/arc/DP160104866en
dc.relation.granthttp://purl.org/au-research/grants/arc/DP170104464en
dc.relation.granthttp://purl.org/au-research/grants/arc/LP160100927en
dc.relation.granthttp://purl.org/au-research/grants/arc/DE160101163en
dc.relation.granthttp://purl.org/au-research/grants/arc/FL170100154en
dc.identifier.pubid389211-
pubs.library.collectionChemistry publicationsen
pubs.library.teamDS10en
pubs.verification-statusVerifieden
pubs.publication-statusPublisheden
dc.identifier.orcidZheng, Y. [0000-0002-2411-8041]en
dc.identifier.orcidJiao, Y. [0000-0003-1329-4290]en
dc.identifier.orcidQiao, S. [0000-0002-1220-1761]en
dc.identifier.orcidVasileff, A. [0000-0003-1945-7740]en
Appears in Collections:Chemistry publications

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