Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/115518
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Type: Journal article
Title: Discovery of halloysite books in altered silicic Quaternary tephras, northern New Zealand
Author: Cunningham, M.
Lowe, D.
Wyatt, J.
Moon, V.
Churchman, G.J.
Citation: Clay Minerals, 2016; 51(3):351-372
Publisher: Cambridge University Press
Issue Date: 2016
ISSN: 0009-8558
1471-8030
Statement of
Responsibility: 
M.J. Cunningham, D.J. Lowe, J.B. Wyatt, V.G. Moon and G. Jock Churchman
Abstract: Hydrated halloysite was discovered in books, a morphology previously associated exclusively with kaolinite. From ∼1.5 to ∼1500 μm in length, the books showed significantly greater mean Fe contents (Fe₂O₃ = 5.2 wt.%) than tubes (Fe₂O₃ = 3.2 wt.%), and expanded rapidly with formamide. They occurred, along with halloysite tubes, spheroids and plates, in highly porous yet poorly permeable, silt-dominated, Si-rich, pumiceous rhyolitic tephra deposits aged ∼0.93 Ma (Te Puna tephra) and ∼0.27 Ma (Te Ranga tephra) at three sites ∼10–20 m stratigraphically below the modern landsurface in the Tauranga area, eastern North Island, New Zealand. The book-bearing tephras were at or near saturation, but have experienced intermittent partial drying, favouring the proposed changes: solubilized volcanic glass + plagioclase→halloysite spheroids→halloysite tubes→halloysite plates→ halloysite books. Unlike parallel studies elsewhere involving both halloysite and kaolinite, kaolinite has not formed in Tauranga presumably because the low permeability ensures that the sites largely remain locally wet so that the halloysite books are metastable. An implication of the discovery is that some halloysite books in similar settings may have been misidentified previously as kaolinite.
Keywords: Halloysite; clay morphology; Fe content; pyroclastic; tephrochronology; Te Ranga tephra; Te Puna tephra; Quaternary
Rights: © The Mineralogical Society of Great Britain and Ireland 2016
RMID: 0030065579
DOI: 10.1180/claymin.2016.051.3.16
Appears in Collections:Agriculture, Food and Wine publications

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