Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/115748
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Type: Journal article
Title: Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: a mechanistic study
Author: Duan, X.
Ao, Z.
Sun, H.
Zhou, L.
Wang, G.
Wang, S.
Citation: Chemical Communications, 2015; 51(83):15249-15252
Publisher: Royal Society of Chemistry
Issue Date: 2015
ISSN: 1359-7345
1364-548X
Statement of
Responsibility: 
Xiaoguang Duan, Zhimin Ao, Hongqi Sun, Li Zhou, Guoxiu Wang and Shaobin Wang
Abstract: Emerging characteristics upon nitrogen-doping were differentiated in the activation of superoxides over single-walled carbon nanotubes. Both experimental and theoretical studies revealed that enhanced peroxymonosulfate (PMS) activation is ascribed to a nonradical process while persulfate (PS) activation is accelerated via directly oxidizing water, yet hydrogen peroxide (H2O2) activation is inert to N-doping. This study details the first insights into versatile N-doping in carbocatalysis for organic oxidation in sustainable remediation.
Description: Published on 10 August 2015
Rights: This journal is © The Royal Society of Chemistry 2015. Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
RMID: 0030095319
DOI: 10.1039/c5cc05101k
Grant ID: http://purl.org/au-research/grants/arc/DP130101319
Appears in Collections:Chemical Engineering publications

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