Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/115748
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Type: | Journal article |
Title: | Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: a mechanistic study |
Author: | Duan, X. Ao, Z. Sun, H. Zhou, L. Wang, G. Wang, S. |
Citation: | Chemical Communications, 2015; 51(83):15249-15252 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2015 |
ISSN: | 1359-7345 1364-548X |
Statement of Responsibility: | Xiaoguang Duan, Zhimin Ao, Hongqi Sun, Li Zhou, Guoxiu Wang and Shaobin Wang |
Abstract: | Emerging characteristics upon nitrogen-doping were differentiated in the activation of superoxides over single-walled carbon nanotubes. Both experimental and theoretical studies revealed that enhanced peroxymonosulfate (PMS) activation is ascribed to a nonradical process while persulfate (PS) activation is accelerated via directly oxidizing water, yet hydrogen peroxide (H2O2) activation is inert to N-doping. This study details the first insights into versatile N-doping in carbocatalysis for organic oxidation in sustainable remediation. |
Description: | Published on 10 August 2015 |
Rights: | This journal is © The Royal Society of Chemistry 2015. Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
DOI: | 10.1039/c5cc05101k |
Grant ID: | http://purl.org/au-research/grants/arc/DP130101319 |
Published version: | http://dx.doi.org/10.1039/c5cc05101k |
Appears in Collections: | Aurora harvest 8 Chemical Engineering publications |
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File | Description | Size | Format | |
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hdl_115748.pdf | Published version | 2.72 MB | Adobe PDF | View/Open |
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