Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/116934
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Type: Journal article
Title: Removal of pertechnetate-related oxyanions from solution using functionalized hierarchical porous frameworks
Author: Banerjee, D.
Elsaidi, S.
Aguila, B.
Li, B.
Kim, D.
Schweiger, M.
Kruger, A.
Doonan, C.
Ma, S.
Thallapally, P.
Citation: Chemistry: A European Journal, 2016; 22(49):17581-17584
Publisher: Wiley
Issue Date: 2016
ISSN: 0947-6539
1521-3765
Statement of
Responsibility: 
Debasis Banerjee, Sameh K. Elsaidi, Briana Aguila, Baiyan Li, Dongsang Kim, Michael J. Schweiger, Albert A. Kruger, Christian J. Doonan, Shengqian Ma and Praveen K. Thallapally
Abstract: Efficient and cost-effective removal of radioactive pertechnetate anions from nuclear waste is a key challenge to mitigate long-term nuclear waste storage issues. Traditional materials such as resins and layered double hydroxides (LDHs) were evaluated for their pertechnetate or perrhenate (the non-radioactive surrogate) removal capacity, but there is room for improvement in terms of capacity, selectivity and kinetics. A series of functionalized hierarchical porous frameworks were evaluated for their perrhenate removal capacity in the presence of other competing anions.
Keywords: Covalent organic frameworks; ion exchange; metal-organic frameworks; nuclear waste; pertechtenate
Rights: © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
DOI: 10.1002/chem.201603908
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Chemical Engineering publications

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