Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/117196
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Type: Journal article
Title: A Poly(ionic liquid) gel electrolyte for efficient all solid electrochemical double-layer capacitor
Author: Taghavikish, M.
Subianto, S.
Gu, Y.
Sun, X.
Zhao, X.
Choudhury, N.
Citation: Scientific Reports, 2018; 8(1):10918-1-10918-10
Publisher: Springer Nature
Issue Date: 2018
ISSN: 2045-2322
2045-2322
Statement of
Responsibility: 
M. Taghavikish, S. Subianto, Y. Gu, X. Sun, X.S. Zhao, N. Roy Choudhury
Abstract: Polyionic liquid based gels have stimulated significant interest due to their wide applications in flexible electronics, such as wearable electronics, roll-up displays, smart mobile devices and implantable biosensors. Novel supported liquid gel electrolyte using polymerisable ionic liquid and an acrylate monomer, has been developed in this work by entrapping ionic liquid during polymerisation instead of post polymerisation impregnation. The chemically crosslinked polyionic liquid gel electrolyte (PIL) is prepared using 2-hydroxyethylmethacrylate (HEMA) monomer and a polymerisable ionic liquid, 1,4-di(vinylimidazolium)butane bisbromide (DVIMBr) in an ionic liquid (IL- 1-butyl-3 methylimidazolium hexafluorophosphate) as the polymerisation solvent, which resulted in in-situ entrapment of the IL in the gel during polymerisation and crosslinking of the polymer. The supported liquid gel electrolyte (SLG) material was characterised with thermal analysis, infrared spectroscopy, and dynamic mechanical analysis, and was found to be stable with good mechanical properties. The electrochemical analysis showed that these chemically cross-linked PIL gel electrolyte-supported ILs are suitable for solid-state, flexible supercapacitor applications.
Rights: © The Author(s) 2018. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
DOI: 10.1038/s41598-018-29028-y
Grant ID: http://purl.org/au-research/grants/arc/FT100100879
http://purl.org/au-research/grants/arc/FL170100101
http://purl.org/au-research/grants/arc/LP110100439
http://purl.org/au-research/grants/arc/DP130101870
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Chemical Engineering publications

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