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Type: Journal article
Title: Magnetic Ni-Co alloy encapsulated N-doped carbon nanotubes for catalytic membrane degradation of emerging contaminants
Author: Kang, J.
Zhang, H.
Duan, X.
Sun, H.
Tan, X.
Liu, S.
wang, S.
Citation: Chemical Engineering Journal, 2019; 362:251-261
Publisher: Elsevier
Issue Date: 2019
ISSN: 1385-8947
Statement of
Jian Kang, Huayang Zhang, Xiaoguang Duan, Hongqi Sun, Xiaoyao Tan, Shaomin Liu, Shaobin Wang
Abstract: Nitrogen-doped carbon nanotubes encapsulated with Ni-Co alloy nanoparticles (NiCo@NCNTs) were readily synthesized by annealing Ni/Co salts with dicyandiamide. The magnetic nanocarbons were assembled as a flat membrane for heterogeneous degradation of organic toxins. The synergistic effect of nitrogen doping and metal alloy encapsulation significantly enhanced the catalytic activity and stability of NCNTs in catalytic activation of peroxymonosulfate (PMS) for purification of an emerging pollutant, ibuprofen. The hybrid catalyst yielded a fast reaction rate of 0.31 min−1, which was 23.4 and 5.8 times higher than that of pristine CNTs and monometallic (Ni or Co) encased CNTs, respectively. The robust membrane catalysis was further confirmed by degrading other organic aqueous pollutants, such as naproxen, sulfachloropyridazine, phenol, methylene blue, and methyl orange. Mechanistic investigation was performed using electron paramagnetic resonance and competitive radical screening tests, which indicated that radical (OH and SO4−) oxidation and nonradical pathway co-existed and played critical roles for catalytic degradation. The study provides a novel advanced oxidation system with catalytic membrane for wastewater remediation.
Keywords: Metal alloy; carbon nanotubes; catalytic degradation; emerging contaminants
Rights: © 2019 Elsevier B.V. All rights reserved.
DOI: 10.1016/j.cej.2019.01.035
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Chemical Engineering publications

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