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Type: Journal article
Title: Boronate Ester Bullvalenes
Author: Patel, H.D.
Tran, T.-.H.
Sumby, C.J.
Pašteka, L.F.
Fallon, T.
Citation: Journal of the American Chemical Society, 2020; 142(8):3680-3685
Publisher: American Chemical Society
Issue Date: 2020
ISSN: 0002-7863
Statement of
Harshal D. Patel, Thanh-Huyen Tran, Christopher J. Sumby, Lukáš F. Pašteka, Thomas Fallon
Abstract: Boronate ester bullvalenes are now accessible in two to four operationally simple steps. This unlocks late-stage diversification through Suzuki cross-coupling reactions to give mono-, di-, and trisubstituted bullvalenes. Moreover, a linchpin strategy enables preprogrammed installation of two different substituents. Analysis of solution phase isomer distributions and single-crystal X-ray structures reveals that isomer preference in the crystal lattice is due to general shape selectivity.
Rights: © 2020 American Chemical Society
RMID: 1000014131
DOI: 10.1021/jacs.9b12930
Grant ID:
Appears in Collections:Chemistry publications

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