Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/127358
Full metadata record
DC FieldValueLanguage
dc.contributor.advisorBeckwith, A.L.J.-
dc.contributor.authorPhillipou, George-
dc.date.issued1974-
dc.identifier.urihttp://hdl.handle.net/2440/127358-
dc.description.abstractThe stercochemistry of the perester-copper salt reaction has been investigated with the cyclic olefins trans-p-menth-2-ene, cis-p-menth-2-ene, 3-methylcyclohexene and 4-methylcyclohexene. The results suggest that the ability of copper to co-ordinate with the double bond directly influences the stereospecificity of the reaction and also the selectivity of the t-butoxy radicals. A stereoelectronic requirement in allyrlic hydrogen atom abstraction has been demonstrated by a kinetic and. product study of the perester-copper reaction with trans and cis-p-menth-2-ene. The result are discussed in terms of product and kinetic studies with reference to a new mechanistic scheme which is tentatively proposed.en
dc.language.isoenen
dc.titleThe perester-copper salt reaction of cyclic olefinsen
dc.typeThesisen
dc.contributor.schoolSchool of Chemistry and Physics : Chemistryen
dc.provenanceThis electronic version is made publicly available by the University of Adelaide in accordance with its open access policy for student theses. Copyright in this thesis remains with the author. This thesis may incorporate third party material which has been used by the author pursuant to Fair Dealing exceptions. If you are the owner of any included third party copyright material you wish to be removed from this electronic version, please complete the take down form located at: http://www.adelaide.edu.au/legalsen
dc.description.dissertationThesis (M.Sc.) -- University of Adelaide, Dept. of Organic Chemistry, 1973en
Appears in Collections:Research Theses

Files in This Item:
File Description SizeFormat 
Phillipou1972_MSc.pdf3.62 MBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.