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|Title:||The perester-copper salt reaction of cyclic olefins|
|School/Discipline:||School of Chemistry and Physics : Chemistry|
|Abstract:||The stercochemistry of the perester-copper salt reaction has been investigated with the cyclic olefins trans-p-menth-2-ene, cis-p-menth-2-ene, 3-methylcyclohexene and 4-methylcyclohexene. The results suggest that the ability of copper to co-ordinate with the double bond directly influences the stereospecificity of the reaction and also the selectivity of the t-butoxy radicals. A stereoelectronic requirement in allyrlic hydrogen atom abstraction has been demonstrated by a kinetic and. product study of the perester-copper reaction with trans and cis-p-menth-2-ene. The result are discussed in terms of product and kinetic studies with reference to a new mechanistic scheme which is tentatively proposed.|
|Dissertation Note:||Thesis (M.Sc.) -- University of Adelaide, Dept. of Organic Chemistry, 1973|
|Provenance:||This electronic version is made publicly available by the University of Adelaide in accordance with its open access policy for student theses. Copyright in this thesis remains with the author. This thesis may incorporate third party material which has been used by the author pursuant to Fair Dealing exceptions. If you are the owner of any included third party copyright material you wish to be removed from this electronic version, please complete the take down form located at: http://www.adelaide.edu.au/legals|
|Appears in Collections:||Research Theses|
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