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https://hdl.handle.net/2440/17818
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DC Field | Value | Language |
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dc.contributor.author | Cole, Marcus Lawford | en |
dc.contributor.author | Davies, Aaron J. | en |
dc.contributor.author | Jones, Cameron | en |
dc.contributor.author | Junk, Peter C. | en |
dc.date.issued | 2005 | en |
dc.identifier.citation | New Journal of Chemistry, 2005; 29 (11):1404-1408 | en |
dc.identifier.issn | 1144-0546 | en |
dc.identifier.uri | http://hdl.handle.net/2440/17818 | - |
dc.description | © Royal Society of Chemistry 2005 | en |
dc.description.abstract | The lithium complexes [Li{N(Ar)C(H)N(Ar)}(pmdeta)], where Ar = 2,6-R₂C₆H₃ (R = Me (1), Et (2) and iPr (3)) and pmdeta = N,N,N’,N’’,N’’-pentamethyldiethylenetriamine, have been synthesised and their solid state structures determined by X-ray methods. Compounds 1–3 comprise a Li(pmdeta) centre coordinated by a bulky formamidinate in either the E-syn or E-anti isomeric form. The structures of compound 3 and one unique molecular unit of compound 1 (E-anti isomer) display coordination of the pendant amidinate imine, and can therefore be considered the first examples of ƞ²:ƞ¹-CQN,N’ metal amidinate coordination. | en |
dc.description.statementofresponsibility | Marcus L. Cole, Aaron J. Davies, Cameron Jones and Peter C. Junk | en |
dc.language.iso | en | en |
dc.publisher | Royal Society Chemistry | en |
dc.source.uri | http://www.rsc.org/publishing/journals/NJ/article.asp?doi=b511519a | en |
dc.title | Bulky formamidinate complexes of lithium: the first examples of ƞ²:ƞ¹-C=N,N' metal amidinate coordination | en |
dc.title.alternative | Bulky formamidinate complexes of lithium: the first examples of n(2):n(1)-C=N,N' metal amidinate coordination | en |
dc.type | Journal article | en |
dc.contributor.school | School of Chemistry and Physics | en |
dc.contributor.school | School of Chemistry and Physics : Chemistry | en |
dc.identifier.doi | 10.1039/b511519a | en |
Appears in Collections: | Chemistry publications |
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