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Type: Journal article
Title: A new approach to the synthesis of carbon chains capped by metal clusters
Author: Bruce, M.
Smith, M.
Zaitseva, N.
Skelton, B.
White, A.
Citation: Journal of Organometallic Chemistry, 2003; 670(1-2):170-177
Publisher: Elsevier Science Sa
Issue Date: 2003
ISSN: 0022-328X
Statement of
Michael I. Bruce, Mark E. Smith, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White
Abstract: Reactions of Co3(μ3-CBr)(μ-dppm)(CO)7 with {Au[P(tol)3]}2{μ-(C6-point triple bond; length half of m-dashC)n} (n=2–4) have given {Co3(μ-dppm)(CO)7}{μ3:μ3-C(C6-point triple bond; length half of m-dashC)nC} [n=2 (1), 3 (2), 4 (3)] containing carbon chains capped by the cobalt clusters. Tetracyanoethene reacts with 2 to give {Co3(μ-dppm)(CO)7}2{μ3:μ3-C(C6-point triple bond; length half of m-dashC)2C[=C(CN)2]C[=C(CN)2]C} (4). X-ray structural characterisation of 1, 3 and 4 are reported, that for 3 being the first of a cluster-capped C10 chain.
Keywords: Carbon chains
Cobalt clusters
Capped clusters
C10 chains
Description: Copyright © 2003 Elsevier Science B.V.
DOI: 10.1016/S0022-328X(02)02186-1
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