Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/17904
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dc.contributor.authorBruce, M.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.contributor.authorZaitseva, N.-
dc.date.issued2003-
dc.identifier.citationJournal of Organometallic Chemistry, 2003; 683(2):398-405-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/2440/17904-
dc.descriptionCopyright © 2003 Elsevier B.V.-
dc.description.abstractComplexes containing a Co3 cluster linked to SiMe3, Au(PPh3), W(CO)3Cp and Fc groups by a C5 chain have been prepared by elimination of AuBr(PR3) (R=Ph, tol) in the reactions between Co3(μ3-CBr)(μ-dppm)(CO)7 and {(R3P)Au}C6-point triple bond; length half of m-dashCC6-point triple bond; length half of m-dashCX [X=SiMe3, W(CO)3Cp] or {(OC)7(μ-dppm)Co3}CC6-point triple bond; length half of m-dashC{Au(PPh3)} and FcC6-point triple bond; length half of m-dashCI (X=Fc). Subsequent auro-desilylation of the SiMe3 compound affords {(OC)7(μ-dppm)Co3}6-point triple bond; length half of m-dashCC6-point triple bond; length half of m-dashCC6-point triple bond; length half of m-dashC{Au[P(tol)3]}. Single-crystal X-ray structures of the W(CO)3Cp, Au{P(tol)3} and Fc complexes are reported. The C5 chain shows little departure from a formal 6-point triple bond; length half of m-dashC---C6-point triple bond; length half of m-dashC---C6-point triple bond; length half of m-dashC--- fragment.-
dc.description.statementofresponsibilityMichael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva-
dc.description.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description-
dc.language.isoen-
dc.publisherElsevier Science Sa-
dc.source.urihttp://dx.doi.org/10.1016/j.jorganchem.2003.08.006-
dc.titlePreparation and molecular structures of some complexes containing C5 chains-
dc.typeJournal article-
dc.identifier.doi10.1016/j.jorganchem.2003.08.006-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest 6
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