Adelaide Research & Scholarship
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https://hdl.handle.net/2440/34456
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| Type: | Journal article |
| Title: | Capsules and star-burst polyhedra : An [Ag[2]L[2]] capsule and a tetrahedral [Ag[4]L[4]] metallosupramolecular prism with cyclotriveratrylene-type ligands |
| Author: | Sumby, C. Hardie, M. |
| Citation: | Angewandte Chemie International Edition, 2005; 44(39):6395-6399 |
| Publisher: | Wiley-V C H Verlag GMBH |
| Issue Date: | 2005 |
| ISSN: | 1433-7851 1521-3773 |
| Abstract: | (Figure Presented) A flexible host: The use of pyridyl-substituted cyclotriveratrylene ligands coupled with geometrically accommodating silver centers has resulted in the isolation and structural characterization of a compact [M2L2] molecular capsule and an [M 4L4] tetrahedral prism (see structure). The former incarcerates two coordinated CH3CN molecules while the latter has an unusual star-burst shape and also acts as host for CH3CN molecules. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA. |
| Keywords: | coordination modes host-guest systems N ligands silver supramolecular chemistry |
| Description: | The definitive version may be found at www.wiley.com |
| DOI: | 10.1002/anie.200501358 |
| Published version: | http://www3.interscience.wiley.com/cgi-bin/abstract/111090207/ABSTRACT |
| Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
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