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Type: Journal article
Title: Building blocks for cyclotriveratrylene-based coordination networks
Author: Hardie, M.
Mills, R.
Sumby, C.
Citation: Organic and Biomolecular Chemistry, 2004; 2(20):2958-2964
Publisher: Royal Soc Chemistry
Issue Date: 2004
ISSN: 1477-0520
Statement of
Michaele J. Hardie, Rachael M. Mills and Christopher J. Sumby
Abstract: The incorporation of three-fold symmetric organic host molecules into coordination polymers should allow for the construction of new and interesting network structures, capable of multiple inclusion behaviour. A range of new multi-dentate bridging ligands/molecular hosts have been prepared by appending nitrogen-containing heterocycles to either cyclotricatechylene, or cyclotriguaiacylene cores. These compounds were obtained in a single-step reaction from readily available precursors, with moderate to good yields, and characterised by a combination of NMR spectroscopy, mass spectrometry and elemental analysis. Two of the new compounds were characterised by X-ray crystallography, revealing different modes of self inclusion behaviour, which indicate the potential importance of -donor stabilisation by CTV derivatives in host–guest chemistry.
Rights: © Royal Society of Chemistry 2004
DOI: 10.1039/B407165D
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