Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/34906
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dc.contributor.authorSumby, C.-
dc.contributor.authorCarr, M.-
dc.contributor.authorFranken, A.-
dc.contributor.authorKennedy, J.-
dc.contributor.authorKilner, C.-
dc.contributor.authorHardie, M.-
dc.date.issued2006-
dc.identifier.citationNew Journal of Chemistry: a journal for new directions in chemistry, 2006; 30(10):1390-1396-
dc.identifier.issn1144-0546-
dc.identifier.issn1369-9261-
dc.identifier.urihttp://hdl.handle.net/2440/34906-
dc.description.abstractFurther examples of a metallo-supramolecular star-burst tetrahedron are reported from reaction of the ligand tris(4-pyridylmethylamino)cyclotriguaiacylene, 1, and AgPF₆ in the presence of dinitrile species, or from reaction of 1 with Ag[1-Ph-closo-1-CB₉H₈-6-I]. Complex [Ag₄(1) ₄(CH₃CN)₃]•4(PF₆)•5(CH₃CN)•(H₂O) has a hexagonal structure where packing of the [Ag₄(1)₄]⁴⁺ tetrahedra mimics the close-packing of spheres. In complex {Ag₄(1)₄(CH₃CN)₂[PhCB₉H₈I]₂}•2[PhCB₉H₈I]•11(CH₃CN) the [1-Ph-closo-1-CB₉H₈-6-I]⁻ anion coordinates to the [Ag₄(1)₄]⁴⁺ tetrahedron through Ag–I and Ag•••H–B interactions, and a less symmetric packing motif is found. The synthesis and crystal structure of the novel monocarbaborane species (NEt₄)[1-Ph-closo-1-CB₉H₈-6-I] are also reported.-
dc.description.statementofresponsibilityChristopher J. Sumby, Michael J. Carr, Andreas Franken, John D. Kennedy, Colin A. Kilner and Michaele J. Hardie-
dc.language.isoen-
dc.publisherRoyal Soc Chemistry-
dc.rights© Royal Society of Chemistry 2006-
dc.titleCrystal-packing motifs of [Ag₄L₄]⁴+ star-burst tetrahedra-
dc.title.alternativeCrystal-packing motifs of [Ag(4)L(4)](4)+ star-burst tetrahedra-
dc.typeJournal article-
dc.identifier.doi10.1039/b609356f-
pubs.publication-statusPublished-
dc.identifier.orcidSumby, C. [0000-0002-9713-9599]-
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