Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/39947
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Type: Journal article
Title: Bismuth tellurides and sulphosalts from the Larga hydrothermal system, Metaliferi Mts., Romania: Paragenesis and genetic significance
Author: Cook, N.
Ciobanu, C.
Citation: Mineralogical Magazine, 2004; 68(2):301-321
Publisher: Mineralogical Society
Issue Date: 2004
ISSN: 0026-461X
1471-8022
Statement of
Responsibility: 
N. J. Cook and C. L. Ciobanu
Abstract: Intermediate levels of the Larga-Fata Baii field, Metaliferi Mts., Romania, are host to epithermal vein mineralization, small skarn-like bodies and ‘geode’-like replacement ores, that together form a complex hydrothermal system rooted in the subjacent andesite stock. Silver-Pb-Bi sulphosalts, some with Sb and/or Se, are intimately associated with hessite and a range of Bi-tellurides with Bi/(Te+S+Se) <=1 (tetradymite, tellurobismuthite, tsumoite, Pb-free rucklidgeite) within all these ore types. Lillianite homologues, both ordered 4L and 7L derivatives (lillianite, gustavite), and disordered varieties are the most abundant sulphosalts, with subordinate bismuthinite derivatives (aikinite, krupkaite, bismuthinite). An exceptionally Ag-rich lillianite homologue, intimately intergrown with tetradymite and hessite, is identified as treasureite on the basis of chemical composition. Porphyry-style mineralization from 600 m beneath the studied level contains rucklidgeite as the single stable Bi-telluride. The trace mineralogy of the system is suggestive of a hydrothermal system strongly zoned with respect to fTe2 and, to a lesser extent, also fS2. Mineralogical and textural evidence suggests that initial crystallization took place at temperatures in excess of 400°C. The association of gold with Bi-minerals is linked to the role of Bimelt as a scavenger for gold, and deposition within ‘droplets’ simultaneous with the formation of arsenopyrite from löllingite + pyrrhotite. Both Bi-tellurosulphides and sulphosalts are commonly non-stoichiometric, a fact that can be correlated with order-disorder in both series. When widely distributed, as in the Larga system, trace amounts of Bi-minerals (sulphosalts, tellurides/ tellurosulphides) have considerable, untapped potential as tracers of the physical-chemical character of an evolving hydrothermal system.
Keywords: tellurides; Bi-sulphosalts; compositional data; Larga; Metaliferi Mts., Romania
Description: © 2004 Mineralogical Society of Great Britain and Ireland
RMID: 0020073101
DOI: 10.1180/0026461046820188
Appears in Collections:Earth and Environmental Sciences publications

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