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Type: Journal article
Title: Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility
Author: Junk, P.
Cole, M.
Citation: Chemical Communications, 2007; 16(16):1579-1590
Publisher: Royal Soc Chemistry
Issue Date: 2007
ISSN: 1359-7345
Statement of
Peter C. Junk and Marcus L. Cole
Abstract: The development of alkali-metal amidinate reagents, in particular formamidinates, has proceeded hand-in-hand with fundamental advances in transition-metal bonding, e.g. metal–metal bonding, and the progressive departure from cyclopentadienyl support ligands in early transition-metal catalysis. This highly personalised account highlights the coordinative versatility of one alkali-metal amidinate subclass; the bis(aryl)formamidinates. These compounds have proven invaluable during transition-metal studies but were considered unworthy of investigation in their own right prior to our work.
Description: © Royal Society of Chemistry 2008
DOI: 10.1039/b613984a
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