Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4396
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Type: Journal article
Title: Preparation and characterisation of the dicarbon cluster complex Ru5(m5-C2)(m-SMe)2(m-PBu2)2(CO)11
Author: Bruce, M.
Adams, C.
Citation: Australian Journal of Chemistry: an international journal for chemical science, 1996; 49(4):517-520
Publisher: CSIRO Publishing
Issue Date: 1996
ISSN: 0004-9425
Abstract: <jats:p>The preparation of the bis -tertiary phosphine C2(Pbu2)2 ( dpba ) is described. Pyrolysis of the ruthenium carbonyl derivative {Ru3(CO)11}2(μ- dbpa ) gives Ru5(μ5-C2PBu2)(μ-PBu2)(CO)13[in 41% overall yield from Ru3(CO)12)] which in turn reacts with Me2S2 to give Ru5(μ5-C2)(μ5-SMe)2(μ-PBu2)2(CO)11(19%). </jats:p>
DOI: 10.1071/CH9960517
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