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Type: Journal article
Title: Diphenylphosphinoyl chloride as a chlorinating agent - The selective double activation of 1,2-diols
Author: Fox, David J.
Pedersen, Daniel Sejer
Petersen, Asger B.
Warren, Stuart
Citation: Organic and Biomolecular Chemistry , 2006; 4 (16):3117-3119
Publisher: Royal Society Chemistry
Issue Date: 2006
ISSN: 1477-0520
School/Discipline: School of Chemistry and Physics : Chemistry
Statement of
David J. Fox, Daniel Sejer Pedersen, Asger B. Petersen and Stuart Warren
Abstract: Treatment of 1,2-diols with diphenylphosphinoyl chloride in pyridine produces beta-chloroethyl phosphinates which react with complete control of stereochemistry to give epoxides and azido-alcohols, useful intermediates in cyclopropane synthesis.
Description: © The Royal Society of Chemistry 2006
DOI: 10.1039/b606881b
Appears in Collections:Chemistry and Physics publications

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