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Type: Journal article
Title: Five oxidation states in metal-bonded C4 chains
Author: Bruce, M.
Denisovich, L.
Low, P.
Peregudova, S.
Ustynyuk, N.
Citation: Mendeleev Communications, 1996; 6(5):200-201
Publisher: Royal Society of Chemistry
Issue Date: 1996
ISSN: 0959-9436
Statement of
Michael I. Bruce, Larisa I. Denisovich, Paul J. Low, Svetlana M. Peregudova and Nikolai A. Ustynyuk
Abstract: The 36-electron diruthenium buta-l,3-diynyl complexes [Ru]C triple bond; length of mdash C–C triple bond; length of mdash C[Ru] [Ru = Ru(PPh3)2Cp and Ru(PMe3)(PPh3)Cp] undergo four stepwise one-electron oxidation–reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidation.
Rights: Copyright status unknown
DOI: 10.1070/MC1996v006n05ABEH000645
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