Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4855
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| Type: | Journal article |
| Title: | Ring Cleavages of Dimethylphenoxide Anions |
| Author: | Dua, S. Bowie, J. |
| Citation: | Rapid Communications in Mass Spectrometry, 1997; 11(18):1996-1998 |
| Publisher: | JOHN WILEY & SONS LTD |
| Issue Date: | 1997 |
| ISSN: | 0951-4198 |
| Abstract: | The major fragmentations of isomeric dimethylphenoxide anions upon collisional activation are losses of H· and Me·. Two minor processes involve the formation of m/z 79 (C6H7-) (-C2H2O) and m/z 77 (C6H5-) [- (Me· + CHO·)]. The former is only observed when (at least) one of the ortho carbons bears a hydrogen substituent, the latter only when there is a 4-methyl substituent. |
| DOI: | 10.1002/(sici)1097-0231(199712)11:18<1996::aid-rcm103>3.3.co;2-a |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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