Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4882
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dc.contributor.authorHamon, David P. G.en
dc.contributor.authorMassy-Westropp, Ralph A.en
dc.contributor.authorRazzino, Pasqualeen
dc.date.issued1995en
dc.identifier.citationTetrahedron, 1995; 51(14):4183-4194en
dc.identifier.issn0040-4020en
dc.identifier.urihttp://hdl.handle.net/2440/4882-
dc.descriptionAvailable online 29 March 2000.en
dc.description.abstractThe derivative of glycine, 8-phenylmenthyl N-Boc-2-bromoglycinate 1 reacted with allyltri-n-butylstannanes via the corresponding radical 2 by the SH2′ mechanism to give (2S) allyl amino acid drrivatives with high diastereoselectivity. The reaction of 1 with triphenyl(1,2-propadienyl)stannane and triphenyl(2-propynyl)stannane gave the (2S) allenyl and (2S) propargyl amino acid derivatives respectively also with high diastereoselectivity but by a different mechanism. The 2-bromoglycinate 1 reacted with various allyltri-n-butylstannanes, triphenyl(1,2-propadienyl)stannane and triphenyl(2-propynyl)stannane to give (2S) unsaturated amino acid derivatives with high diastereoselectivity.en
dc.description.statementofresponsibilityDavid P.G. Hamon, Ralph A. Massy-Westropp and Pasquale Razzinoen
dc.language.isoenen
dc.publisherPergamonen
dc.rightsCopyright © 1995 Published by Elsevier Ltd.en
dc.titleAsymmetric induction in acyclic radical reactions: Enantioselective syntheses of a-Amino acids via carbon-carbon bond forming radical reactionsen
dc.typeJournal articleen
dc.contributor.schoolSchool of Chemistry and Physics : Chemistryen
dc.identifier.doi10.1016/0040-4020(95)00134-Ten
Appears in Collections:Chemistry publications

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