Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/49908
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Type: Journal article
Title: The network of hydrogen bonding in kingite, as revealed by a neutron-diffraction investigation of its deuterated analogue, AL₃(PO₄)₂F₃·₇D₂O
Other Titles: The network of hydrogen bonding in kingite, as revealed by a neutron-diffraction investigation of its deuterated analogue, AL(3)(PO(4))(2)F(3)(.)(7)D(2)O
Author: Wallwork, K.
Pring, A.
Taylor, M.
Hunter, B.
Citation: Canadian Mineralogist: crystallography, geochemistry, mineralogy, petrology, mineral deposits, 2004; 42(1):135-141
Publisher: Mineralogical Assoc Canada
Issue Date: 2004
ISSN: 0008-4476
1499-1276
Statement of
Responsibility: 
Kia S. Wallwork, Allan Pring, Max R. Taylor and Brett A. Hunter
Abstract: The extensive hydrogen-bonding network of kingite is described for a specimen from Tom's Quarry, near Kapunda, South Australia. After deuteration, the triclinic structure was refined in space group P1̄, a 9.318(1), b 10.092(1), c 7.108(1) Å, α 97.61(1), β 100.56(1), γ 95.97(1)°, V 645.7(1) Å3, Z=2. The formula of this modified specimen of kingite, refined using neutron powder-diffraction data, has been established as Al3(PO4)2F3·7D2O. We were able to locate the three atoms of fluorine.
Keywords: kingite
deuteration
Rietveld refinement
neutron
powder diffraction
hydrogen bond
Rights: © 2004 Mineralogical Association of Canada
DOI: 10.2113/gscanmin.42.1.135
Published version: http://dx.doi.org/10.2113/gscanmin.42.1.135
Appears in Collections:Aurora harvest
Earth and Environmental Sciences publications

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