Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/51873
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Some alkynyl-ruthenium complexes containing di-imine and tertiary phosphine ligands |
Author: | Bruce, M. Hall, B. Skelton, B. White, A. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2008; 634(6-7):1097-1101 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2008 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Benjamin C. Hall, Brian W. Skelton, and Allan H. White |
Abstract: | <jats:title>Abstract</jats:title><jats:p>Reactions between <jats:styled-content>$\rm [RuCl_{2}(PPh_{3})_{2}(Bu^{t}_{2}bpy)]$<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/tex2gif-ueqn-1.gif" xlink:title="equation image" /></jats:styled-content>, (<jats:bold>1</jats:bold>), and terminal alkynes in the presence of Tl[PF<jats:sub>6</jats:sub>], followed by chromatography on alumina, have given the mono‐alkynyl complexes <jats:styled-content>$\rm [RuCl(C{\equiv}CR)(PPh_{3})_{2}(Bu^{t}_{2}bpy)]$<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/tex2gif-ueqn-2.gif" xlink:title="equation image" /></jats:styled-content> (R = Ph <jats:bold>2</jats:bold>, C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NO<jats:sub>2</jats:sub>−4 <jats:bold>3</jats:bold>, CO<jats:sub>2</jats:sub>Me <jats:bold>4</jats:bold>, Fc <jats:bold>5</jats:bold>, CPh<jats:sub>2</jats:sub>(OH) <jats:bold>6</jats:bold>), of which the single‐crystal XRD molecular structures of <jats:bold>3</jats:bold>, <jats:bold>4</jats:bold> and <jats:bold>5</jats:bold> are reported.</jats:p> |
Keywords: | Alkynyl Ruthenium Crystal structure Phosphine ligand |
Description: | Article first published online: 5 MAY 2008 |
Rights: | Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/zaac.200800020 |
Published version: | http://dx.doi.org/10.1002/zaac.200800020 |
Appears in Collections: | Aurora harvest Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.