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https://hdl.handle.net/2440/66430
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dc.contributor.author | Abdul-Kadir, M. | - |
dc.contributor.author | Hanton, L.R. | - |
dc.contributor.author | Sumby, C.J. | - |
dc.date.issued | 2011 | - |
dc.identifier.citation | Dalton Transactions: an international journal of inorganic chemistry, 2011; 40(45):12374-12380 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.issn | 1477-9234 | - |
dc.identifier.uri | http://hdl.handle.net/2440/66430 | - |
dc.description.abstract | A series of metallo-macrocyclic based coordination polymers has been prepared from flexible amide ligands N-6-[(3-pyridylmethylamino)carbonyl]-pyridine-2-carboxylic acid (L1-CH(3)) and N-6-[(4-pyridylmethylamino)carbonyl]-pyridine-2-carboxylic acid (L2-CH(3)). In all but one case, self-assembled dinuclear metallo-macrocyclic units form the basis of the polymeric structures, whereby discrete metal centres, and dinuclear or trinuclear clusters, are linked by the self-assembled macrocycles to give 1D and 2D coordination polymers. In one instance, a 1D coordination polymer is formed in a reaction carried out under ambient conditions; when the same reaction is conducted under solvothermal conditions a 2D structure is formed. In all but two of these structures, the polymeric chains and nets are close-packed within the crystals. In the case of a 6,3-connected 2D coordination polymer {[Cd(3)(L2-CH(3))(3)(NO(3))(L2)(CH(3)OH)](NO(3))(2)·12½H(2)O}(n) (9), small oval channels percolate down the a-axis of the unit cell. | - |
dc.language.iso | en | - |
dc.publisher | Royal Society of Chemistry | - |
dc.source.uri | http://dx.doi.org/10.1039/c1dt10853k | - |
dc.title | Self-assembled metallo-macrocycle based coordination polymers with unsymmetrical amide ligands | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/c1dt10853k | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/FT0991910 | - |
dc.relation.grant | DP0773011 | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/DP0773011 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Sumby, C.J. [0000-0002-9713-9599] | - |
Appears in Collections: | Aurora harvest 5 Environment Institute publications IPAS publications |
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