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https://hdl.handle.net/2440/69492
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Type: | Journal article |
Title: | Electron transfer through α-peptides attached to vertically aligned carbon nanotube arrays: a mechanistic transition |
Other Titles: | Electron transfer through alpha-peptides attached to vertically aligned carbon nanotube arrays: a mechanistic transition |
Author: | Yu, J. Zvarec, O. Huang, D. Bissett, M. Scanlon, D. Shapter, J. Abell, A. |
Citation: | Chemical Communications, 2012; 48(8):1132-1134 |
Publisher: | Royal Soc Chemistry |
Issue Date: | 2012 |
ISSN: | 1359-7345 1364-548X |
Statement of Responsibility: | Jingxian Yu, Ondrej Zvarec, David M. Huang, Mark A. Bissett, Denis B. Scanlon, Joe G. Shapter and Andrew D. Abell |
Abstract: | The mechanism of electron transfer in α-aminoisobutyric (Aib) homoligomers is defined by the extent of secondary structure, rather than just chain length. Helical structures (Aib units ≥3) undergo an electron hopping mechanism, while shorter disordered sequences (Aib units <3) undergo an electron superexchange mechanism. |
Keywords: | Nanotubes, Carbon Aminoisobutyric Acids Peptides Protein Structure, Secondary Electron Transport Kinetics Models, Molecular |
Description: | This article is part of the Artificial photosynthesis web themed issue |
Rights: | Journal © The Royal Society of Chemistry 2012 |
DOI: | 10.1039/c2cc16665h |
Grant ID: | http://purl.org/au-research/grants/arc/DP0985176 http://purl.org/au-research/grants/arc/DP0985176 |
Published version: | http://dx.doi.org/10.1039/c2cc16665h |
Appears in Collections: | Aurora harvest 5 IPAS publications |
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