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https://hdl.handle.net/2440/73272
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DC Field | Value | Language |
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dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Le Guennic, B. | - |
dc.contributor.author | Scoleri, N. | - |
dc.contributor.author | Zaitseva, N. | - |
dc.contributor.author | Halet, J. | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | Organometallics, 2012; 31(13):4701-4706 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.issn | 1520-6041 | - |
dc.identifier.uri | http://hdl.handle.net/2440/73272 | - |
dc.description.abstract | Several symmetric and asymmetric bis(metalla-diynediyl)ruthenium(II) complexes of the general formula trans-{L xRu} C≡CC≡C{Ru(dppe) 2}C≡CC≡C{RuL′ y} (L x, L′ y = (PPh 3) 2Cp, (dppe)Cp, (dppe)Cp*), containing Ru(dppe) 2 as the central linking group, have been successfully synthesized and characterized spectroscopically. DFT calculations show that their HOMO's are delocalized over the Ru-C 4-Ru-C 4-Ru chain, suggesting that there is electronic interaction between the terminal RuL x groups through the C 4 chains and the Ru(dppe) 2 center. Limited electrochemical measurements reveal that the complexes undergo a series of five stepwise reversible or quasi-reversible oxidation processes. © 2012 American Chemical Society. | - |
dc.description.statementofresponsibility | Michael I. Bruce, Boris Le Guennic, Nancy Scoleri, Natasha N. Zaitseva, and Jean-François Halet | - |
dc.language.iso | en | - |
dc.publisher | Amer Chemical Soc | - |
dc.rights | Copyright © 2012 American Chemical Society | - |
dc.source.uri | http://dx.doi.org/10.1021/om3000949 | - |
dc.title | Extending metal-capped polyynediyl molecular wires by insertion of inorganic metal units | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1021/om3000949 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 5 Chemistry publications |
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