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Type: Journal article
Title: Total synthesis of (+)-aureol
Author: Kuan, K.
Pepper, H.
Bloch, W.
George, J.
Citation: Organic Letters, 2012; 14(18):4710-4713
Publisher: Amer Chemical Soc
Issue Date: 2012
ISSN: 1523-7060
Statement of
Kevin K. W. Kuan, Henry P. Pepper, Witold M. Bloch, and Jonathan H. George
Abstract: A total synthesis of the marine sponge meroterpenoid (+)-aureol has been achieved in 12 steps (6% overall yield) from (+)-sclareolide. Key steps of the synthesis include a biosynthetically inspired sequence of 1,2-hydride and methyl shifts, and a biomimetic cycloetherification reaction.
Keywords: Animals; Porifera; Diterpenes; Sesquiterpenes; Marine Biology; Molecular Structure; Stereoisomerism
Rights: ©2012 American Chemical Society
RMID: 0020122862
DOI: 10.1021/ol301715u
Appears in Collections:Chemistry publications
IPAS publications

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