Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/84480
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Type: Journal article
Title: A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO₂
Other Titles: A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO(2)
Author: Burgun, A.
Crees, R.
Cole, M.
Doonan, C.
Sumby, C.
Citation: Chemical Communications, 2014; 50(79):11760-11763
Publisher: Royal Society of Chemistry
Issue Date: 2014
ISSN: 1364-548X
1364-548X
Statement of
Responsibility: 
Alexandre Burgun, Rachel S. Crees, Marcus L. Cole, Christian J. Doonan and Christopher J. Sumby
Abstract: A new MOF, [Zn4O{Cu(L)2}2] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L)2] NHC linkers. MOF 1 possesses tetrahedral Zn4O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L)2] linkers, and 14 A 1-D pore channels lined with [Cu(L)2] moieties that catalyse the hydroboration of CO2.
Description: Includes supplementary information
Rights: This journal is © The Royal Society of Chemistry 2014
RMID: 0030006840
DOI: 10.1039/C4CC04761C
Grant ID: http://purl.org/au-research/grants/arc/FT100100400
http://purl.org/au-research/grants/arc/FT0991910
Appears in Collections:Chemistry and Physics publications

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