Adelaide Research & Scholarship
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https://hdl.handle.net/2440/85854
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| Type: | Journal article |
| Title: | The stereochemistry of the adducts derived from the Diels-Alder addition of cyclobutenes and cyclopentadienones: a caveat on some existing PMR methods for the assignment of stereochemistry |
| Author: | Warrener, R.N. Tan, R.Y.S. Russell, R.A. |
| Citation: | Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry, 1979; 20(31):2943-2946 |
| Publisher: | Pergamon Press |
| Issue Date: | 1979 |
| ISSN: | 0040-4039 1873-3581 |
| Statement of Responsibility: | Ronald N. Warrener, Richard Y.S. Tan, Richard A. Russell |
| Abstract: | The stereochemistry of the adducts formed from the cycloaddition of tetracyclone, phencyclone and 2-methyl-3,4,5-triphenylcyclopenta-2,4-dienone with cis-3,4-dichlorocyclobutene (in one case with 3-chloro-4-methoxycyclobutene) has been evaluated in a rigorous fashion. This allows a firmly-based caveat to be issued regarding the p.m.r. probe for stereochemical evaluation of tetracyclone adducts recently proposed by Coxon and Battiste. |
| Rights: | © Pergamon Press Ltd. 1979. |
| DOI: | 10.1016/S0040-4039(01)86459-5 |
| Appears in Collections: | Aurora harvest 7 Chemistry publications |
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