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Type: Journal article
Title: Probing post-synthetic metallation in metal-organic frameworks: insights from X-ray crystallography
Author: Bloch, W.
Burgun, A.
Doonan, C.
Sumby, C.
Citation: Chemical Communications, 2015; 51(25):5486-5489
Publisher: Royal Society of Chemistry
Issue Date: 2015
ISSN: 1359-7345
Statement of
Witold M. Bloch, Alexandre Burgun, Christian J. Doonan and Christopher J. Sumby
Abstract: For post-synthetic metallation (PSMet) of a metal–organic framework (MOF, [Mn3(L2)(L')] = 1) we show a solvent dependency for the form of the metallated product. PSMet of 1 with MnCl2 in ethanol leads to a single metal entity per coordinating site while acetonitrile yields a remarkably complex multiply metallated product; thus, determining the extent of metallation requires an intimate understanding of the chemistry occurring in the MOF pores.
Rights: This journal is ©The Royal Society of Chemistry 2015
DOI: 10.1039/c4cc09639h
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