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http://hdl.handle.net/2440/92439
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Type: | Journal article |
Title: | Probing post-synthetic metallation in metal-organic frameworks: insights from X-ray crystallography |
Author: | Bloch, W. Burgun, A. Doonan, C. Sumby, C. |
Citation: | Chemical Communications, 2015; 51(25):5486-5489 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2015 |
ISSN: | 1359-7345 1364-548X |
Statement of Responsibility: | Witold M. Bloch, Alexandre Burgun, Christian J. Doonan and Christopher J. Sumby |
Abstract: | For post-synthetic metallation (PSMet) of a metal–organic framework (MOF, [Mn3(L2)(L')] = 1) we show a solvent dependency for the form of the metallated product. PSMet of 1 with MnCl2 in ethanol leads to a single metal entity per coordinating site while acetonitrile yields a remarkably complex multiply metallated product; thus, determining the extent of metallation requires an intimate understanding of the chemistry occurring in the MOF pores. |
Rights: | This journal is ©The Royal Society of Chemistry 2015 |
RMID: | 0030020142 |
DOI: | 10.1039/c4cc09639h |
Grant ID: | http://purl.org/au-research/grants/arc/FT100100400 http://purl.org/au-research/grants/arc/FT0991910 |
Appears in Collections: | IPAS publications |
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