Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/96243
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Type: Journal article
Title: Formation of Fe₂O₃ microboxes with hierarchical shell structures from metal-organic frameworks and their lithium storage properties
Other Titles: Formation of Fe(2)O(3) microboxes with hierarchical shell structures from metal-organic frameworks and their lithium storage properties
Author: Zhang, L.
Wu, H.
Madhavi, S.
Hng, H.
Lou, X.
Citation: Journal of the American Chemical Society, 2012; 134(42):17388-17391
Publisher: American Chemical Society
Issue Date: 2012
ISSN: 0002-7863
1520-5126
Statement of
Responsibility: 
Lei Zhang, Hao Bin Wu, Srinivasan Madhavi, Huey Hoon Hng, and Xiong Wen (David) Lou
Abstract: Fe(2)O(3) microboxes with hierarchically structured shells have been synthesized simply by annealing Prussian blue (PB) microcubes. By utilizing simultaneous oxidative decomposition of PB microcubes and crystal growth of iron oxide shells, we have demonstrated a scalable synthesis of anisotropic hollow structures with various shell architectures. When evaluated as an anode material for lithium ion batteries, the Fe(2)O(3) microboxes with a well-defined hollow structure and hierarchical shell manifested high specific capacity (~950 mA h g(-1) at 200 mA g(-1)) and excellent cycling performance.
Keywords: Organometallic Compounds
Rights: © 2012 American Chemical Society
RMID: 0030036936
DOI: 10.1021/ja307475c
Appears in Collections:Chemical Engineering publications

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