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|Title:||Formation of Fe₂O₃ microboxes with hierarchical shell structures from metal-organic frameworks and their lithium storage properties|
|Other Titles:||Formation of Fe(2)O(3) microboxes with hierarchical shell structures from metal-organic frameworks and their lithium storage properties|
|Citation:||Journal of the American Chemical Society, 2012; 134(42):17388-17391|
|Publisher:||American Chemical Society|
|Lei Zhang, Hao Bin Wu, Srinivasan Madhavi, Huey Hoon Hng, and Xiong Wen (David) Lou|
|Abstract:||Fe(2)O(3) microboxes with hierarchically structured shells have been synthesized simply by annealing Prussian blue (PB) microcubes. By utilizing simultaneous oxidative decomposition of PB microcubes and crystal growth of iron oxide shells, we have demonstrated a scalable synthesis of anisotropic hollow structures with various shell architectures. When evaluated as an anode material for lithium ion batteries, the Fe(2)O(3) microboxes with a well-defined hollow structure and hierarchical shell manifested high specific capacity (~950 mA h g(-1) at 200 mA g(-1)) and excellent cycling performance.|
|Rights:||© 2012 American Chemical Society|
|Appears in Collections:||Chemical Engineering publications|
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