Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/96244
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dc.contributor.authorFabretto, M.en
dc.contributor.authorEvans, D.en
dc.contributor.authorMueller, M.en
dc.contributor.authorZuber, K.en
dc.contributor.authorHojati-Talemi, P.en
dc.contributor.authorShort, R.en
dc.contributor.authorWallace, G.en
dc.contributor.authorMurphy, P.en
dc.date.issued2012en
dc.identifier.citationChemistry of Materials, 2012; 24(20):3998-4003en
dc.identifier.issn0897-4756en
dc.identifier.issn1520-5002en
dc.identifier.urihttp://hdl.handle.net/2440/96244-
dc.description.abstractThe reduced pressure synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) with sheet-like morphology has been achieved with the introduction of an amphiphilic triblock copolymer into the oxidant thin film. Addition of the copolymer not only results in an oxidant thin film which remains liquid-like under reduced pressure but also induces structured growth during film formation. PEDOT films were polymerized using the vacuum vapor phase polymerization (VPP) technique, in which we show that maintaining a liquid-like state for the oxidant is essential. The resulting conductivity is equivalent to commercially available indium tin oxide (ITO) with concomitant optical transmission values. PEDOT films can be produced with a variety of thicknesses across a range of substrate materials from plastics to metals to ceramics, with sheet resistances down to 45 Ω/□ (ca. 3400 S·cm–1), and transparency in the visible spectrum of >80% at 65 nm thickness. This compares favorably to ITO and its currently touted replacements.en
dc.description.statementofresponsibilityManrico V. Fabretto, Drew R. Evans, Michael Mueller, Kamil Zuber, Pejman Hojati-Talemi, Rob D. Short, Gordon G. Wallace, and Peter J. Murphyen
dc.language.isoenen
dc.publisherAmerican Chemical Societyen
dc.rights© 2012 American Chemical Societyen
dc.subjectvapor phase polymerization; PEDOT; high conductivity; organic electronicsen
dc.titlePolymeric material with metal-like conductivity for next generation organic electronic devicesen
dc.typeJournal articleen
dc.identifier.rmid0030016659en
dc.identifier.doi10.1021/cm302899ven
dc.identifier.pubid152051-
pubs.library.collectionChemical Engineering publicationsen
pubs.library.teamDS02en
pubs.verification-statusVerifieden
pubs.publication-statusPublisheden
Appears in Collections:Chemical Engineering publications

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