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Type: Journal article
Title: Hetero-bimetallic metal-organic polyhedra
Author: Teo, J.
Coghlan, C.
Evans, J.
Tsivion, E.
Head-Gordon, M.
Sumby, C.
Doonan, C.
Citation: Chemical Communications, 2016; 52(2):276-279
Publisher: Royal Society of Chemistry
Issue Date: 2016
ISSN: 1364-548X
Statement of
Jesse M. Teo, Campbell J. Coghlan, Jack D. Evans, Ehud Tsivion, Martin Head-Gordon, Christopher J. Sumby, and Christian J. Doonan
Abstract: Porous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of -12 kJ mol(-1).
Description: First published online 26 Oct 2015
Rights: © the author. This journal is ©The Royal Society of Chemistry 2015.
DOI: 10.1039/c5cc08336b
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