A covalent deprotection strategy for assembling supramolecular coordination polymers from metal-organic cages
Date
2020
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Schneider, M.L.
Linder-Patton, O.M.
Bloch, W.M.
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Chemical Communications, 2020; 56(85):12969-12972
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Matthew L. Schneider, Oliver M. Linder-Patton and Witold M. Bloch
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Abstract
A Cu4L4 metal-organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline-copper coordination and possess a tunable porosity based on the rate of deprotection.
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This journal is © The Royal Society of Chemistry 2020