Imogolite prepared from cement kiln dust removes arsenite from water
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Date
2023
Authors
Gonzalez, A.
Manquian Cerda, K.
Maldonado, T.
Calderon, R.
Sarkar, B.
Arancibia Miranda, N.
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Environmental Technology & Innovation, 2023; 31(103142):1-13
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Imogolite belongs to the family of nanotubular metal oxides which are useful for the construction of new materials in nanotechnology. This study aims to develop a simple waste valorization method to obtain imogolite from cement kiln dust (CKD) via solubilization of CKD and subsequent precipitation of imogolite (Imo-CKD) in a hydrothermal process. The newly synthesized Imo-CKD and a conventional imogolite (Imo) showed similar diameter (Ø) and length (L) of nanotubes [Ø≅ 1.9 nm and L ≅ 200 nm] and crystallinity grade but different values of isoelectric point (IEP) [IEPImo−CKD=8.86 and IEPImo=9.92]. The shift in the IEP value of Imo-CKD to a lower value was attributed to the presence of allophane as a subproduct during Imo-CKD synthesis. Arsenite [As(III)] removal from water by both the imogolites was a rapid (t ≤ 20 min) and spontaneous process. The kinetic As(III) removal data obeyed the pseudo-second order model, while surface diffusion also controlled the As(III) adsorption process. The activation energy (Ea > 40 kJ mol−1) suggested a chemical adsorption of As(III) in both materials. The Imo-CKD (0.377 mmol g−1) removed As(III) from water more efficiently than Imo (0.334 mmol g−1), despite the formation of allophane byproduct in the synthesis process. Results of this study can promote the reuse of inexpensive CKD as a viable alternative to replace costly tetraethyl orthosilicate for imogolite synthesis and use of imogolite for water pollutant removal.
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Copyright 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/)