Disulfide-bridged (Mo3S11) cluster polymer: molecular dynamics and application as electrode material for a rechargeable magnesium battery
Date
2016
Authors
Truong, Q.D.
Devaraju, M.K.
Nguyen, D.N.
Gambe, Y.
Nayuki, K.
Sasaki, Y.
Tran, P.D.
Honma, I.
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Advisors
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Journal article
Citation
Nano Letters, 2016; 16(9):5829-5835
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Abstract
Exploring novel electrode materials is critical for the development of a next-generation rechargeable magnesium battery with high volumetric : capacity. Here, we showed that a distinct amorphous molybdenum sulfide, :being a coordination polymer of disulfide-bridged (Mo3S11) clusters, has great,potential as a rechargeable magnesium battery cathode.. This material provided good reversible capacity, attributed to its unique structure with high flexibility and capability of deformation upon Mg insertion. Free terminal disulfide moiety May: act as the:active site for reversible insertion and, extraction of magnesium.
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Data source: Supporting information, http://pubs.acs.org/doi/suppl/10.1021/acs.nanolett.6b02593
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Copyright 2016 American Chemical Society